posted on 2023-12-17, 15:04authored byJi-Jun Zeng, Bo Zhao, Yu An, Xiao-Bo Tang, Sheng Han, Zhi-Qiang Yang, Wei Zhang, Jian Lu
A new series of complex anion ionic liquids (ILs) [Emim][BF3X] (X = CH3SO3, EtSO4, HSO4, Tosylate) were synthesized and characterized by nuclear
magnetic resonance, elemental analysis, differential scanning calorimetry
analysis, and thermogravimetry. The physicochemical properties of
these ILs, such as density, viscosity, conductivity, and surface tension,
were measured and correlated with thermodynamic and empirical equations
in the temperature range of 293.15–358.15 K under ambient conditions,
and the thermal expansion coefficient, standard molar entropy, lattice
potential energy, viscosity activation energy, surface enthalpy, and
surface entropy were further calculated from experimental values.
According to the temperature-dependent viscosity and conductivity,
[Emim][BF3X] ILs follow the Walden rule, and they are classified
as “good (or super) ionic liquids”.