posted on 2024-01-03, 20:06authored byKai Zhao, Zhen Bao, Qi Liu
CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (PNCs)
have been recognized as potential optoelectronic materials due to
their excellent optical characteristics. However, their poor stability
limits their further practical application, and research on their
stability improvement mainly concentrated on green-emitted CsPbBr3 PNCs. Herein, high-stable red, green, and blue three-primary
color CsPbX3-nanocrystal/SiO2 (PNC/SiO2) luminescent composites have been synthesized by a simple high-temperature
melt-crystallization method, which did not use any solvent or ligand.
The sintering conditions for PNC/SiO2 composites were optimized
according to the X-ray diffraction and photoluminescence (PL) spectra,
which ensured the composite structures and achieved higher PL quantum
yield. The optimized red, green, and blue composites can remain at
99%, 90%, and 82% PL intensity after 15 heating loops, performing
good thermal stability. To check the application potential, the optimized
composites were fabricated as red, green, and blue light-emitting
diodes (LEDs), showing high color purity to consist of a wide color
gamut. The red, green, and blue LEDs remained at 83%, 82%, and 96%
emission intensity and kept their color coordinates after a long working
duration, showing excellent stability. The excellent stability and
relatively higher color purity of the PNC/SiO2 composites
indicate their great potential for commercial background display applications.