posted on 2021-06-07, 15:04authored byYuxin Chen, Po Hu, Zhiyun Huang, Jinyu Wang, Haiyang Song, Xi Chen, Xiao Lin, Tianmin Wu, Xiaodi Tan
Relying on various
defects and functional oxygen-containing groups
on the basal planes, graphene oxide (GO) is commonly unitized for
intimate mixing with a polymer matrix to fabricate high-performance
nanocomposite polymeric materials with the characteristics of graphene.
Herein, by introducing GO nanosheets in a phenanthraquinone-doped
polymethyl methacrylate (PQ/PMMA) photopolymer, we demonstrate that
the polarization holographic diffraction efficiency of nanocomposite
materials can be dramatically enhanced up to nearly 10 times and the
photosensitivity can also be enhanced by more than 3 times. Experimental
observations reveal that the incorporation of GO nanosheets serves
as a polymerization initiator not only to promote the polymerization
of MMA monomers and induce the drafting behavior of the PMMA polymer
on its surface but also to effectively modulate the molecular weight
of the PQ/PMMA photopolymer by adjusting the doping concentration
of GO nanosheets. The current study, for the first time, demonstrates
that the modulation of molecular weight for PQ/PMMA photopolymers
here exerts a significant impact on their holography performance.
In addition, due to the strong physisorption of PQ photosensitizers
onto GO nanosheets, the aggregation of PQ around GO-graft-PMMA also
facilitates the formation of GO-graft-PMMA/PQ and is beneficial to
the enhancement of holographic performance. The emergence of GO-graft-PMMA/PQ
nanocomposite materials here is expected to fulfill the requirement
of high-performance polarization-sensitive materials in the field
of polarization holographic data storage and provide a facile but
effective nanocomposite doping strategy to modulate the holographic
performance of photopolymers from micro- and mesoscopic levels.