posted on 2021-12-21, 21:13authored byWei Li, Jun Ma, Santiago Garcia, Chongjie Gao, Ruochen Liu, Jingjing Qiu, Feng Zhao, Shiren Wang
The
controllable aggregation of nanoparticles in solution is an
important but unsolved problem in nanotechnology, which is mainly
hindered by the symmetrical structure of the nanoparticles. Here,
we propose an anisotropic semishell nanostructure to achieve the rod-shaped
assembly of nanoparticles in solution. The isotropic Au@silica core–shell
nanoparticles are self-assembled on the silicon wafer by the drop-casting
technique to form a monolayer film. Au@silica semishell nanoparticles
are obtained after selectively removing part of the silica shell by
reactive ion etching. After functionalization with pH-sensitive 4-mercaptobenzoic
acid molecules, the semishell nanoparticles display pH-responsive
localized surface plasmon resonance coupling and near-infrared light
absorption, thereby holding great potential for noninvasive photothermal
therapy.