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Preparation and Characterization of Parent Phenylphosphinidene and Its Oxidation to Phenyldioxophosphorane: The Elusive Phosphorus Analogue of Nitrobenzene
journal contribution
posted on 2017-03-24, 00:00 authored by Artur Mardyukov, Dominik Niedek, Peter R. SchreinerTriplet
phenylphosphinidene was prepared by light-induced elimination
of ethylene from the corresponding phenylphosphirane and was characterized
by IR and UV/vis spectroscopy together with matching of its spectral
data with density functional theory computations. The photolysis of
phenylphosphirane in 3P-O2 doped
matrices enabled the spectroscopic identification of a hitherto unknown
phenyldioxophosphorane, the long elusive phosphorus analogue of nitrobenzene.
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Parent Phenylphosphinidenephotolysispectroscopic identificationphenylphosphiraneethylenedensityOxidationphenyldioxophosphoranePhenyldioxophosphoranephosphorus analogueIRspectroscopymatricePreparationElusive Phosphorus AnalogueO 2datanitrobenzenelight-induced eliminationtheory computationsCharacterizationUV3 PNitrobenzene Triplet phenylphosphinidene
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