Much attention has been paid to compound
a ZIF-8 antibacterial
agent with textiles for recycling. However, antibacterial inactivation
may be caused by dissolution of the ZIF-8 antibacterial agent in postfinishing
technology. In this work, a nondissolution-bonded T-ZIF-8-PEG-TPU
photocatalyst was prepared by covalent immobilization, and then, bonded
antibacterial fibers T-ZIF-8-PEG-TPU were fabricated by electrospinning
technology. The microstructure of the fibers was regulated by optimizing
the spinning solution concentration, PEG content, and conductive salt
content. The optimum process parameters are 22 wt % spinning solution,
3.3 wt % PEG, and 0.5 wt % ZnCl2 conductive salt. The intrinsic
relationship between the fiber microstructure and photocatalytic antibacterial
property, moisture permeability, and hydrophobicity was investigated.
The antibacterial rate of the fiber membrane against Staphylococcus aureus reaches 100% after 30 min of
visible light irradiation, and the antibacterial rate of Escherichia coli is 99.6% after visible light irradiation
for 120 min. The fiber membrane has a standard grade I moisture permeability
rate and a certain waterproof effect. It has potential applications
in the field of health protection such as medical dressings and medical
protective products.