posted on 2021-07-22, 13:34authored byN. K. Murugasenapathi, K. A. Esther Jebakumari, S. Jamal Mohamed, K. Giribabu, Tamilarasan Palanisamy
Investigating the behavior of analytes
at the electrode surface
is crucial in understanding the electrochemical and electrocatalytic
reactions. Although Surface Enhanced Raman Scattering (SERS) is sensitive
to minor chemical changes in the analyte, it is not widely used to
study the reaction mechanisms on nonplasmonic surfaces because of
the interference from plasmonic SERS substrates. In this study, we
have investigated the redox reaction of Nile Blue A on a glassy carbon
surface using pinhole-free silica-coated silver nanoparticles for
Raman signal enhancement. The silver nanostructures were synthesized
by a chemical reduction method, and the quality of the silica layer
was confirmed using microscopic and electrochemical method. The in situ spectroelectrochemical data reveals the catalytic
interference from silver which considerably alters the native reaction
mechanism. The pinhole-free silica layer prevents the hot electron
transfer and yields an interference-free enhancement to the Raman
signals.