posted on 2023-12-10, 14:03authored byHanqing Gu, Xiaohu Yang, Song Chen, Wenming Zhang, Hui Ying Yang, Zhanyu Li
Aluminum-ion
batteries have garnered an extensive amount of attention
due to their superior electrochemical performance, low cost, and high
safety. To address the limitation of battery performance, exploring
new cathode materials and understanding the reaction mechanism for
these batteries are of great significance. Among numerous candidates,
multiple structures and valence states make manganese-based oxides
the best choice for aqueous aluminum-ion batteries (AAIBs). In this
work, a new cathode consists of γ-MnO2 with abundant
oxygen vacancies. As a result, the electrode shows a high discharge
capacity of 481.9 mAh g–1 at 0.2 A g–1 and a sustained reversible capacity of 128.6 mAh g–1 after 200 cycles at 0.4 A g–1. In particular,
through density functional theory calculation and experimental comparison,
the role of oxygen vacancies in accelerating the reaction kinetics
of H+ has been verified. This study provides insights into
the application of manganese dioxide materials in aqueous AAIBs.