Oxidative Radical
Transnitrilation of Arylboronic
Acids with Trityl Isocyanide

Xu, Zhiyuan; Liang, Xiaojuan; Li, Huan

doi:10.1021/acs.orglett.2c03778.s001

ol2c03778_si_001.pdf (3.3 MB)

Oxidative Radical Transnitrilation of Arylboronic Acids with Trityl Isocyanide

journal contribution

posted on 2022-12-15, 13:34 authored by Zhiyuan Xu, Xiaojuan Liang, Huan Li

We report a radical transnitrilation of arylboronic acids with trityl isocyanide in the presence of manganese(III) acetate. Many functional groups can be tolerated in this transformation, and a special positive effect of benzoic acid in this reaction has been observed.