On the Stereospecific Conversion of
Proximally-Oxygenated Trisubstituted
Vinyltriphenylstannanes into
Stereodefined Trisubstituted Alkenes

Dimopoulos, Paschalis; Athlan, Audrey; Manaviazar, Soraya; Hale, Karl J.

doi:10.1021/ol051935t.s001

ol051935t_si_001.pdf (4.73 MB)

On the Stereospecific Conversion of Proximally-Oxygenated Trisubstituted Vinyltriphenylstannanes into Stereodefined Trisubstituted Alkenes

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posted on 2005-11-24, 00:00 authored by Paschalis Dimopoulos, Audrey Athlan, Soraya Manaviazar, Karl J. Hale

Allylically oxygenated vinyl α-triphenylstannanes such as 22 can be readily converted into vinyl iodides and thereafter stereodefined trisubstituted alkenes with retention of configuration.

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Stereodefined retention Alkene Vinyltriphenylstannane oxygenated Trisubstituted triphenylstannane Allylically configuration stereodefined trisubstituted alkenes Stereospecific Conversion vinyl iodides

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