NaCl-Type Frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), the First
Examples Containing μ1,3-Nitrito Bridges Showing Antiferromagnetism

Liu, Tao; Chen, Yi-Hong; Zhang, Yan-Juan; Wang, Zhe-Ming; Gao, Song

doi:10.1021/ic060759x.s003

ic060759x_si_003.pdf (257.67 kB)

NaCl-Type Frameworks of [M(pyrazine)₂NO₂]ClO₄ (M = Co, Cu), the First Examples Containing μ_1,3-Nitrito Bridges Showing Antiferromagnetism

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posted on 2006-11-13, 00:00 authored by Tao Liu, Yi-Hong Chen, Yan-Juan Zhang, Zhe-Ming Wang, Song Gao

Two new 3D NaCl-type frameworks of [M(pyrazine)₂NO₂]ClO₄ (M = Co, Cu), consist of (4, 4) sheets of metal−pyrazine connected by μ_1,3-nitrito, representing the first examples of μ_1,3-nitrito bridges and exhibiting antiferromagnetism.

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Bridges Containing nitrito Framework AntiferromagnetismTwo antiferromagnetism framework First Co Nitrito Cu

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NaCl-Type Frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), the First Examples Containing μ1,3-Nitrito Bridges Showing Antiferromagnetism