posted on 2023-12-26, 21:45authored byYinhu Pan, Shichao Du, Yan Wang, Qilei Sun, Fumin Xue
The solid–liquid equilibrium solubility of dicyandiamide
(DCD) in five kinds of binary solvent mixtures (water + ethanol, water
+ n-propanol, water + N,N-dimethylformamide (DMF), water + acetonitrile, and DMF
+ ethyl acetate) at T = (283.15–323.15) K
was determined by gravimetric method. The solubility of DCD in the
five groups of binary mixed solvents increases with the increase of
temperature. In the mixed solvent of water + DMF, the solubility of
DCD decreases monotonically with the increase in water content. And
in the mixed solvent of DMF + ethyl acetate, the solubility of DCD
monotonically increases with the increase of DMF content. Among the
other three mixed solvents, with the increase of the water component,
the solubility of DCD first increases and then decreases after reaching
the peak. The maximum solubility value in water + ethanol, water + n-propanol, and water + acetonitrile is reflected when the
water ratio is 0.6. The modified Apelblat model, van’t Hoff
model, λh model, Apelblat–Jouyban–Acree
model, and the nonrandom two-liquid model were used to correlate the
solubility data. The results show that the modified Apelblat model
has the best correlation with the solubility of DCD.