Janus Metal–Organic Frameworks/Wood Aerogel Composites for Boosting Catalytic Performance by Le Châtelier’s Principle

Elaborate design of metal–organic frameworks (MOFs) composites with enhanced properties is of fundamental interest and practical importance in the fields of catalysis. Typical strategies are usually focused on how to increase MOFs contents while lacking architecture design for performance improvements. Herein, we first report MOFs composites with Janus structures to boost catalytic performance by Le Châtelier’s principle when using wood aerogel as a versatile platform. Janus structures mean that one part of the composite is still wood aerogel while the other part is decorated with MOFs. The underoil hydrophilicity of the wood aerogels endows the Janus composites with dehydration capacity for promoting the equilibrium movement so as to boost the catalytic performance. The catalytic performance of Janus composites for the Knoevenagel reaction increases more than 40% compared with those symmetric composites. Moreover, both the final conversion and the reaction rate are much better for the Janus composites than other state-of-the-art heterogeneous ZIF-8-based catalysts. Our design is general and paves the way to exploit composites with special architecture.