Intramolecular [4 + 2] Cycloadditions of
Benzynes with Conjugated Enynes,
Arenynes, and Dienes

Hayes, Martin E.; Shinokubo, Hiroshi; Danheiser, Rick L.

doi:10.1021/ol051372l.s001

ol051372l_si_001.pdf (1.47 MB)

Intramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and Dienes

journal contribution

posted on 2005-09-01, 00:00 authored by Martin E. Hayes, Hiroshi Shinokubo, Rick L. Danheiser

Benzynes generated by the reaction of o-(trimethylsilyl)aryl triflates with TBAT participate in intramolecular [4 + 2] cycloadditions with conjugated enynes, arenynes, and dienes to furnish highly condensed polycyclic aromatic compounds.

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Keywords

Arenyne compound diene intramolecular cycloaddition enyne arenyne Conjugated Enynes TBAT polycyclic trimethylsilyl triflate Dienes Benzynes Intramolecular Cycloaddition

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