Insight into the Water-Triggered Conversion of Cs4PbBr6/Mesoporous Silica-Based Nanocomposites: In
Situ Formation, Water Responsiveness, and Multistage Anticounterfeiting
posted on 2023-11-29, 21:29authored byBoyang Zhou, Meizhi Han, Yan He, Ruizhen Qian, Wei Xiong, Chunyu Zhao, Ling He, Aizhao Pan
Cs4PbX6 (X = Cl, Br, and I)-type all-inorganic
lead halide perovskite nanocrystals (PNCs) have unique optoelectronic
properties. However, their luminescence behavior demands a more in-depth
study. Herein, we demonstrated a nanoconfinement strategy to fabricate
a mesoporous silica nanoparticles and Cs4PbBr6 (MSNs@Cs4PbBr6) nanocomposite. Hexagonal Cs4PbBr6 nanocrystals (NCs) with an average particle
size of 20 nm were formed in situ in the mesopores of MSNs. Benefited
by crystal-phase conversion induced by water, MSNs@Cs4PbBr6 showed water-luminescence responsiveness, implying its feasibility
for fabricating a highly stable and highly sensitive water sensor.
The water test paper fabricated by dispersing MSNs@Cs4PbBr6 powder displayed a clear discrimination at the treated boundary
line under UV light, indicating excellent sensitivity of the coated
test paper in water detection. Furthermore, MSNs@Cs4PbBr6 was examined as an optical anticounterfeiting material for
building a multilevel anticounterfeiting system. This work provides
a new insight for fabricating multilevel anticounterfeiting systems
based on perovskite-based materials.