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Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions
journal contribution
posted on 2019-10-11, 14:46 authored by Tim Krappitz, Kristina Jovic, Florian Feist, Hendrik Frisch, Vincent P. Rigoglioso, James P. Blinco, Andrew J. Boydston, Christopher Barner-KowollikWe introduce the
hybrid copolymerization of two disparate monomer
classes (vinyl monomers and ring-strained cyclic olefins) via living
photopolymerization. The living character of the polymerization technique
(metal-free photo-ROMP) is demonstrated by consecutive chain-extensions.
Further, we propose a mechanism for the copolymerization and analyze
the copolymer structure in detail by high-resolution mass spectrometry.
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polymerization techniquemass spectrometryHybrid Photo-induced Copolymerizationcopolymer structurecopolymerizationRing-Strainedmechanismring-strained cyclic olefinsVinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditionsmonomer classesvinyl monomersphotopolymerizationchain-extensionmetal-free photo-ROMP
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