ic1c01905_si_002.pdf (10.38 MB)
Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
Version 2 2021-08-26, 20:30
Version 1 2021-08-23, 21:14
journal contribution
posted on 2021-08-26, 20:30 authored by Borja Rodríguez-Barea, Júlia Mayans, Renato Rabelo, Adrián Sanchis-Perucho, Nicolás Moliner, José Martínez-Lillo, Miguel Julve, Francesc Lloret, Rafael Ruiz-García, Joan CanoThe coexistence of
field-induced blockage of the magnetization
and significant magnetocaloric effects in the low-temperature region
occurs in a mononuclear holmium(III) diethylenetriamine-N,N,N′,N″,N″-pentaacetate complex, whose gadolinium(III)
analogue is a commercial MRI contrast agent. Both properties make
it a suitable candidate for cryogenic magnetic refrigeration, thus
enlarging the variety of applications of this simple class of multifunctional
molecular nanomagnets.
