99Tc is
a radioactive fission product, mainly in the
form of TcO4–, with good solubility and
mobility in the environment. The development of effective and inexpensive
materials to remove TcO4– from nuclear
industry wastewater or contaminated water is significant. Wood sawdust
is a byproduct of the wood processing industry and is an abundant,
low-cost, and sustainable material. The mesostructure of wood consists
of numerous hollow cells that are joined endwise to form an interconnected
channel matrix capable of rapid transfer of ions. Imidazolium-functionalized
wood sawdust (IM-WS) was synthesized using natural wood sawdust by
a two-step reaction. It has excellent properties of TcO4–/ReO4– adsorption
including rapid adsorption dynamics (30 s to equilibrium), good adsorption
stability (pH 3–9), high selectivity (adsorption of 45.4 Re
% in 1000 times excess of NO3– ions,
76.6 Re % in 6000 times excess of SO42– ions, and 92.2 Tc % in a simulated mixed solution; after adsorption,
the concentration of TcO4– decreased
to 0.056 ppb from the initial concentration of 12.09 ppb in 1000 times
excess of SO42−), and in particular low
production costs. These characteristics give it great prospects for
low-level radioactive wastewater treatment and environmental remediation.