Highly Efficient, Flexible, and Eco-Friendly Manganese(II) Halide Nanocrystal Membrane with Low Light Scattering for High-Resolution X‑ray Imaging

Scintillators enable invisible X-ray to be converted into ultraviolet (UV)/visible light that can be collected using a sensor array and is the core component of the X-ray imaging system. However, combining the excellent properties of high light output, high spatial resolution, flexibility, non-toxicity, and cost effectiveness into a single X-ray scintillator remains a great challenge. Herein, a novel scintillator based on benzyltriphenylphosphonium manganese(II) bromide (BTP₂MnBr₄) nanocrystal (NC) membranes was developed by the in situ fabrication strategy. The long Mn–Mn distance provided by the large BTP cation allows the nonradiative energy dissipation in this manganese(II) halide to be significantly suppressed. As a result, the flexible BTP₂MnBr₄ NC scintillator shows an excellent linear response to the X-ray dose rate, a high light yield of ∼71,000 photon/MeV, a low detection limit of 86.2 nGy_air/s at a signal-to-noise ratio of 3, a strong radiation hardness, and a long-term thermal stability. Thanks to the low Rayleigh scattering associated with the dense distribution of nanometer-scale emitters, light cross-talk in X-ray imaging is greatly suppressed. The impressively high-spatial resolution X-ray imaging (23.8 lp/mm at modulation transfer function = 0.2 and >20 lp/mm for a standard pattern chart) was achieved on this scintillator. Moreover, well-resolved 3D dynamic rendering X-ray projections were also successfully demonstrated using this scintillator. These results shed light on designing efficient, flexible, and eco-friendly scintillators for high-resolution X-ray imaging.