High-Performance Structural Supercapacitors Based on Aligned Discontinuous Carbon Fiber Electrodes and Solid Polymer Electrolytes

This paper presents an investigation of the potential to use aligned discontinuous carbon fiber dry prepregs as electrodes in structural supercapacitors (SSCs). The high fiber-matrix interfacial bonding of the structural composite was achieved by adopting a solid polymer electrolyte, consisting of poly­(vinylidene), lithium triflate, and epoxy. Processing of the SSC was carried out via dip-coating of the polymer electrolyte and then cured using a vacuum bag. The electrochemical performance of the SSCs was measured before and after mechanical loading. The microstructures of the SSCs as-fabricated and damaged under flexural loading were identified by μ-CT imaging. An SSC with a specific capacitance of 0.128 mF/cm² (11.62 mF/g), a flexural strength of 47.49 MPa, and a flexural modulus of 8.48 GPa has been achieved, demonstrating significant improvements in mechanical properties over those of SSCs based on woven carbon fiber fabric-based electrodes. The mechanical behavior of the supercapacitors was evaluated by both quasi-static and cyclic flexural loading tests. The excellent electrochemical stability of the supercapacitors was validated by a capacitance retention of above 96% under galvanostatic charge–discharge cycling tests. The knowledge gained in this work will benefit future research in the optimization of SSC performance.