posted on 2024-02-01, 15:36authored byD. S. Wang, X. Q. Zheng, J. W. Xu, L. H. He, Y. W. Gao, H. Huang, H. Wu, X. Y. Cao, D. Liu, J. X. Shen, G. Y. Wang, J. Y. Zhang, Y. F. Wu, F. X. Hu, S. G. Wang, B. G. Shen
We
present herein a systematic study of a polycrystalline
magnetocaloric
compound ErFe2Si2. It exhibits a transition
from the antiferromagnetic to the paramagnetic phase around 3.0 K
according to magnetic and heat capacity measurements. Neutron powder
diffraction revealed that ErFe2Si2 possesses
a superlattice magnetic structure with a propagation vector of (0,
0, 0.5). The superlattice magnetic structure can be modeled by a transverse
spin density wave (cosine-modulated) or a spiral type, which cannot
be distinguished solely by neutron powder diffraction (NPD) pattern
fitting. The stability of different types of magnetic structures was
also investigated by first-principles calculations. The ErFe2Si2 compound shows a giant magnetocaloric effect with
a maximal negative magnetic entropy change and an adiabatic temperature
change of 11.5 J/kg K and 5.7 K, respectively, under the field change
of 0–1 T. The large low-field magnetocaloric effect is related
to its low critical field of metamagnetic transition and its low quasi-saturation
magnetic field. The excellent performance of ErFe2Si2 makes this compound a potential magnetocaloric material for
applications at liquid helium temperatures.