posted on 2021-06-29, 20:45authored byXianyu Liu, Tayyaba Najam, Ghulam Yasin, Mohan Kumar, Miao Wang
Herein, we successfully
synthesized two novel metal thiophosphites
(MTPs) hybridized with carbon, that is, NiPS3/C and SnPS3/C composites, via an environment-friendly and cost-effective
approach without harsh reaction conditions. Subsequently, the electrochemical
performances of NiPS3/C and SnPS3/C composites
have been investigated in coin-cells, and it is revealed that MTPs/C
have a significantly higher Li-storage capacity and better stability
compared to the MTPs without carbon. Moreover, the SnPS3/C electrode shows a lower internal resistance and a better rate
performance compared to NiPS3/C. We employed extensive
ex situ experiments to characterize the materials and interpreted
the remarkably improved performance of MTPs/C.