Para-xylene
(PX) is one of the most crucial aromatic raw materials
in petrochemical industry. It is urgent to develop a more low-cost
and efficient PX production process due to the growing demand for
PX. This paper introduces ultrasound into the PX crystallization process
and analyzes the data of supersolubility, metastable zone width, and
induction period of PX under different working conditions. Based on
the classical nucleation theory and the cluster coalescence model,
the PX crystallization characteristics and the mechanism of ultrasound
enhancement are investigated. The results can be concluded as follows.
Ultrasound significantly reduces the metastable zone width and induction
period of the PX crystallization process, speeds up the crystal nucleation
rate, and prevents the explosion nucleation. When the supersaturation
is above 1.055, the PX nucleation mechanism is homogeneous nucleation,
and when it is below 1.055, the PX nucleation mechanism is heterogeneous
nucleation. The crystal growth mechanism is continuous growth. The
PX-dominated cluster at the mesoscale contains 14 monomers. The formation
period of clusters is accelerated by ultrasound, and the critical
nucleation radius and critical nucleation free energy of PX are both
dramatically decreased. The system’s diffusion coefficient
is improved by ultrasound, which also lowers the interfacial tension
and the surface entropy factor corresponding to the two nucleation
mechanisms. When the ultrasonic power changes from 0 to 88 W, the
crystal nucleation rate constant increases by 22.4 times and the diffusion
coefficient by 11.86 times. Theoretically, this study might enable
future PX crystallization process improvements.