Environmental Applications of Biobased Polydopamine-β-Cyclodextrin-Epichlorohydrin
Supramolecular Hydrogel with Tuneable Swelling and Selective Adsorption
Behaviors
posted on 2024-03-08, 17:04authored byXuze Hu, Li Hu, Jianming Wan, Meiying Huang, Yida Deng, Zijun Qiu, Junsheng Qi, Changjun Zou
Supramolecular
hydrogels have been extensively studied for environmental
applications owing to their biocompatible, nontoxic, and cost-effective
properties. Herein, a polydopamine-β-cyclodextrin-epichlorohydrin
(PDA-β-CD-EP) supramolecular hydrogel was facilely prepared
through one-pot polymerization using a molar ratio of dopamine (DA)/β-cyclodextrin
(β-CD)/epichlorohydrin (EP) of 1/2/50. Compared with other hydrogels,
the (PDA-β-CD-EP) supramolecular hydrogel can selectively adsorb
malachite green from mixed dyes. The structure, surface morphology,
and thermostability of the PDA-β-CD-EP supramolecular hydrogels
were illustrated by FT-IR, SEM–EDX, and TGA-DTG, respectively.
Interestingly, the PDA-β-CD-EP-2 supramolecular hydrogel exhibited
excellent pH-responsive swelling behavior. The influences of the pH,
adsorption time, dosage, and initial concentration were systematically
studied. Under optimal conditions, the maximum adsorption capacity
of the PDA-β-CD-EP-2 supramolecular hydrogel was 652.1 mg/g
for MG according to the Langmuir fitting results, much higher than
those of the other adsorbents. More importantly, the PDA-β-CD-EP-2
supramolecular hydrogel possessed good reproducibility, reusability,
and biodegradability. Besides, the selective adsorption mechanism
was proposed and proved, such as hole size and shape effect, electrostatic
force, and host–guest interaction. Overall, this study could
provide a method to prepare a PDA-β-CD-EP-2 supramolecular hydrogel
as a biosorbent for wastewater remediation.