posted on 2024-03-15, 19:16authored byFuqiang Li, Ying Li, Zhongkai Yu, Xiangrui Du, Eunhye Yang, Yoomi Ahn, Xiaofeng Huang, Bo Ram Lee, Sung Heum Park
Quasi-two-dimensional (quasi-2D) Ruddlesden–Popper
(RP)
perovskites, exemplified by BA2Csn–1PbnBr3n+1 (BA = butylammonium, n > 1), show promise
as efficient emitters. However, their electroluminescence performance
is limited by a significant energy loss during carrier transportation.
Herein we use 2-methylthiophene-3-carboxylic acid (MeTCA), which forms
robust hydrogen-bonding interactions with the spacer BA cations, to
reconstruct the quasi-2D perovskite structure. This reconstruction
enhances the energy transfer in perovskite films, thereby improving
the light emission efficiency. Additionally, MeTCA reduces the defect
density in RP perovskites by acting as an electron-rich Lewis base
and eliminating uncoordinated Pb2+. Consequently, we achieve
a photoluminescence quantum yield of up to 83.22% for the quasi-2D
perovskite prepared by using the MeTCA additive strategy. Furthermore,
we successfully fabricate high-efficiency quasi-2D perovskite light-emitting
diodes with a maximum external quantum efficiency of 21.73% and a
current efficiency of 70.30 cd A–1.