posted on 2022-01-21, 20:08authored byYi-Shin Chen, Zhen Bao, Wen-Tse Huang, Agata Lazarowska, Natalia Majewska, Sebastian Mahlik, Grzegorz Leniec, Slawomir M. Kaczmarek, Hsiao-Yu Huang, Chun-I Wu, Di-Jing Huang, Ru-Shi Liu
Organic–inorganic
hybrid metal halides have recently attracted
attention in the global research field for their bright light emission,
tunable photoluminescence wavelength, and convenient synthesis method.
This study reports the detailed properties of (C10H16N)2MnBr4, which emits bright green
light with a high photoluminescence quantum yield. Results of powder
X-ray diffraction, photoluminescence, thermogravimetric analysis,
and Raman spectra show the phase transition of (C10H16N)2MnBr4 at 430 K. This phase transition
was identified as the solid to liquid state of (C10H16N)2MnBr4. Moreover, the pressure- and
temperature-induced relationship between structural and optical properties
in (C10H16N)2MnBr4 can
be identified. This investigation provides deep insights into the
luminescent properties of metal halide crystals and promotes further
research.