Two-dimensional
Ruddlesden–Popper perovskites (2D RPPs)
have attracted tremendous research interest because of their excellent
photoelectric performance and environmental stability. However, a
fundamental understanding of the intrinsic fluorescence characteristics
is still limited, and the origin of dual-emission peaks in 2D RPPs
is under intense debate. In this work, high-quality 2D (BA)2PbBr4 single crystals that were synthesized using a novel
one-step cooling crystallization method exhibited obvious dual blue
emission peaks at 412 and 432 nm under wide-field excitation. Space-
and time-resolved photoluminescence (PL) spectra of mechanically exfoliated
flakes under one- and two-photon excitation reveal that a single high-energy
exciton emission was observed from the excitation spot, which underwent
a remarkable redshift after propagation. The results can be well fit
by the photon recycling model. Our results confirmed that the PL peak
at 412 nm originates from the exciton emission at the excitation spot,
while the PL peak at 432 nm was induced by photon recycling and long-range
waveguide assisted by total internal reflection. Our findings emphasize
the importance of photon recycling in the optical spectrum or the
exciton kinetics in 2D layered perovskites. Moreover, the 2D perovskite
with inner-plane directional photon recycling and a waveguide effect
exhibits great potential in constructing high-performance optoelectronic
devices.