posted on 2024-02-19, 12:03authored byQiwen Sun, Luning Chai, Song Chen, Wenming Zhang, Hui Ying Yang, Zhanyu Li
A dual-salt
electrolyte with 5 M Al(OTF)3 and
0.5 M
LiOTF is proposed for aqueous aluminum batteries, which can effectively
prevent the corrosion caused by the hydrogen evolution reaction. With
the addition of LiOTF in the electrolyte, the solvation phenomenon
has changed with the coordination mode of Al3+ conversion
from an all octahedral structure to a mixed octahedral and tetrahedral
structure. This change can reduce the hydrogen bond between water
molecules, which will minimize the occurrence of hydrogen evolution
reactions. Moreover, the new electrolyte improves the cycle life of
the battery. With MnO as the cathode, 2.1 V high charging platform
and 1.5 V high discharge platform can be obtained. The electrochemical
stability window (ESW) has been improved to 3.8 V. The first cycle
capacity is up to 437 mAh g–1, which can be maintained
at 103 mAh g–1 after 100 cycles. This work provides
solutions for the future development of electrolyte for aqueous aluminum
batteries.