posted on 2021-06-18, 14:34authored byFrancesco Maddalena, Aozhen Xie, Xin Yu Chin, Raihana Begum, Marcin E. Witkowski, Michal Makowski, Benoit Mahler, Winicjusz Drozdowski, Stuart Victor Springham, Rajdeep Singh Rawat, Nripan Mathews, Christophe Dujardin, Muhammad Danang Birowosuto, Cuong Dang
Lead
halide perovskite (LHP) nanocrystals (NCs) have recently attracted
attention due to both their high quantum yield and their potential
for X-ray imaging applications. In this paper, we investigated the
scintillation properties of three different LHP NCs; CsPbBr3, FAPbBr3, and CsPbI3. The featured NCs exhibited
high X-ray excited luminescence (XL) at cryogenic temperatures. While
FAPbBr3 and CsPbI3 NCs display thermal quenching,
CsPbBr3 NCs show negative thermal quenching and high XL
at high temperatures, with a light yield of 24,000 ± 2,100 photons/MeV
at 300 K. The LHP NCs exhibit a small afterglow and low trap density
and exhibit a very fast XL decay time, under 20 ns, faster than those
of some currently used commercial scintillators. Overall, CsPbBr3 NCs are the best performing materials investigated here,
making them particularly attractive for fast-timing applications such
as positron emission tomography or particle detectors in high-energy
physics. In the end, we demonstrate the proof of concept for using
a CsPbBr3 NC matrix for imaging applications and the flexibility
of NCs for developing microstructure scintillators.