Designing a Multifunctional Catalyst for the Direct Production of Gasoline-Range Isoparaffins from CO₂

The production of carbon-neutral fuels from CO₂ presents an avenue for causing an appreciable effect in terms of volume toward the mitigation of global carbon emissions. To that end, the production of isoparaffin-rich fuels is highly desirable. Here, we demonstrate the potential of a multifunctional catalyst combination, consisting of a methanol producer (InCo) and a Zn-modified zeolite beta, which produces a mostly isoparaffinic hydrocarbon mixture from CO₂ (up to ∼85% isoparaffin selectivity among hydrocarbons) at a CO₂ conversion of >15%. The catalyst combination was thoroughly characterized via an extensive complement of techniques. Specifically, operando X-ray absorption spectroscopy (XAS) reveals that Zn (which plays a crucial role of providing a hydrogenating function, improving the stability of the overall catalyst combination and isomerization performance) is likely present in the form of Zn₆O₆ clusters within the zeolite component, in contrast to previously reported estimations.