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DDE in Sediments of the Palos Verdes Shelf, California: In Situ Transformation Rates and Geochemical Fate
journal contribution
posted on 2008-09-01, 00:00 authored by Robert P. Eganhouse, James PontolilloFrom 1947 to 1971 the world’s largest manufacturer of DDT
discharged process wastes into the sewers of Los Angeles County. Roughly
870–1450 t of DDT were released to the ocean off Palos Verdes,
CA, a portion of which (∼100 t) resides in sediments on the
continental shelf and slope. The most abundant DDT compound in the
sediments, p,p′-DDE, is degrading by reductive
dechlorination, but the rate of transformation and factors controlling
it are not well understood. In order to estimate in situ transformation rates and predict the long-term fate of p,p′-DDE, box cores were collected in 1992 and 2003 from a single
location on the Palos Verdes Shelf and analyzed for 8 DDT compounds
and 84 polychlorinated biphenyl (PCB) congeners. The PCBs show no
evidence of dechlorination, and inventories did not change between
1992 and 2003. By contrast, the inventory of p,p′-DDE
decreased by 43%, whereas that of p,p′-DDMU,
the putative reductive dechlorination product, increased by 34%. The
first-order transformation rate for p,p′-DDE
at the study site is 0.051 ± 0.006 yr−1. A
multistep reaction model suggests that inventories of p,p′-DDE and p,p′-DDMU will continue
to decline, whereas that of p,p′-DDNU will
reach a maximum around 2014.
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Situ Transformation RatesDDT compoundPalos Verdesstudy sitesedimentDDEtransformation rateprocess wastes8 DDT compoundsCAmultistep reaction model84 polychlorinated biphenylPalos Verdes ShelfLos Angeles CountyPCBs showtransformation ratesGeochemical FateFrom 1947reductive dechlorinationreductive dechlorination product
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