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Cubic Phase Sn-Rich GeSn Nanocrystals in a Ge Matrix
journal contribution
posted on 2014-04-02, 00:00 authored by Alexander A. Tonkikh, Nikolay D. Zakharov, Alexandra A. Suvorova, Christian Eisenschmidt, Joerg Schilling, Peter WernerWe
report on the synthesis of a novel optoelectronic material,
Sn-rich Ge1–xSnx nanocrystals in a Ge matrix. The nanocrystals have been formed
after annealing of a metastable Ge-rich Ge1–ySny film, which was embedded in
the Ge matrix. Electron microscopy investigations have revealed that
these nanocrystals possess two lattice types: (i) a diamondlike cubic
structure with a high Sn fraction (x > 0.5) and
(ii)
an ordered zincblende structure (x = 0.5).