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Confined Growth of Cu-Doped CeO2 Nanostructures in Boron-Rich Carbon Frameworks for Acetone Oxidation

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posted on 2021-09-16, 13:13 authored by Qingling Liu, Xueqian Wu, Rui Han, Caihong Pang, Shuang Xing, Lizhe Yang, Chunfeng Song, Na Ji, Xuebin Lu, Degang Ma
The design and synthesis of low-cost, excellent catalytic activity catalysts is the key to catalytic oxidation of VOCs. Nanomaterials have attracted great interest in recent years. Here, a simple impregnation method was used to synthesize the Cu-doped CeO2 nanostructure catalyst supported on a boron-rich carbon carrier and applied for the catalytic oxidation of acetone. After trace amounts of Cu were added to the single CeO2 supported on boron-rich carbon catalyst, Cu-doped CeO2 catalyst displayed better catalytic activity. Besides, it also has long-term stability and H2O resistance. The influence of copper doping on the performance of the catalyst was studied by many characterization technologies. The result indicated that the introduction of Cu can further limit the growth of CeO2 grains based on the limited growth of metal nanoparticles on the carrier, can make the amounts of Ce3+ and adsorb oxygen species increase, and can enhance the redox properties of CeO2. Therefore, Cu-doped CeO2 nanostructures in a boron-rich carbon catalyst have the potential for the removal of acetone.

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