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Catalytic conversion of chicken fats into fuel grade hydrocarbons

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journal contribution
posted on 2024-02-19, 08:40 authored by Sourav Sutradhar, Md Razaul Karim, Md Zakir Hossain

Fatty acid is considered as a renewable source for producing transportation fuel. As there is an ongoing price hike of diesel and kerosene as well as a lack of sustainable fuel to mitigate global climate change, the current study developed a one-step process of fuel grade hydrocarbons production from low-grade chicken fats (as a fatty acid source) using NiO/γ-Al2O3 catalysts. Results showed that straight-chain hydrocarbons were obtained through deoxygenation of chicken fats at different temperatures (350 to 400 °C) and reaction times (0.25 to 1 h). 65% liquid yield and 87% degree of deoxygenation were obtained at the optimum reaction conditions (400 °C and 1 h) using 5 wt%NiO/γ-Al2O3 catalyst, whereas the liquid product contains 18.7% C8 to C15 alkanes, 38.5% hexadecane, 39% heptadecane and 3.8% C18 to C20 alkanes. Liquid product has a similar high heating value (HHV) and density as a commercial fuel such as diesel. This work opens a new research window in the field of green energy to improve global energy security.

Funding

This work is supported by SUST (Shahjalal University of Science and Technology) Research Centre, Sylhet, Bangladesh (Project ID # AS/2019/2/12) and BANBIES (Bangladesh Bureau of Educational Information and Statistics) under the Ministry of Education, Bangladesh (Project ID # SD2019846). We thank Bangladesh Council of Scientific and Industrial Research, Dhaka, Bangladesh for conducting GC analysis of the liquid products. We would also like to thank Professor Paul A. Charpentier, Director, Laboratory of Environmentally Friendly Solvents and Advanced Materials, Department of Chemical & Biochemical Engineering, Western University, London, ON, Canada for providing the opportunity to conduct ATR-FTIR, TG-DTA and TPO analysis.

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