Catalytic Upgrading of Cellulose Pyrolysis Volatiles
over Ce Modified Hierarchical ZSM‑5 Zeolite: Insight into the
Effect of Acid Properties on
Light Aromatics and Catalyst Stability
CeO2 receives extensive
researches as an active component
due to its providential catalytic center and favorable reducibility.
Herein, a series of Ce-modified hierarchical ZSM-5 zeolites (FZ5)
were prepared by HF (0.5 mol/L) etching followed by impregnation with
different Ce loadings. The role of incorporating extra-framework Ce
elements was assessed by catalytic upgrading of the cellulose pyrolysis
volatiles to produce light aromatics (LAs). Introducing CeO2 could effectively regulate the acid properties of catalysts with
an increase in Lewis acid sites and a decrease in Brönsted
acid sites, which could significantly improve the catalytic performance.
As a result, the selectivity toward LAs were significantly enhanced
and the coke content dramatically decreased. The highest selectivity
to LAs and the lowest coke content obtained over 1.0Ce-FZ5 zeolite
(loading 1.0 wt % Ce) were 84.0% and 2.42 wt %, respectively. Additionally,
the 1.0Ce-FZ5 catalyst exhibited excellent stability, maintaining
nearly 90% carbon yield of LAs after the seventh regeneration test.
CeO2 modification opened a simple and feasible way for
promoting the LAs selectivity and catalyst stability during the reforming
of biomass volatiles.