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Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds

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posted on 2010-08-25, 00:00 authored by Masato Ito, Chika Kobayashi, Akio Himizu, Takao Ikariya
Highly enantioselective hydrogenative desymmetrization of bicyclic imides has been developed with chiral Cp*Ru(PN) catalysts. The present hydrogenation directly provides stereochemically well-defined cyclic compounds with excellent enantiomeric exessses, which might otherwise require a detour to reach.

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    Journal of the American Chemical Society

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    Functionalized Chiral Cyclic CompoundsHighly enantioselective hydrogenative desymmetrizationcyclic compoundshydrogenationEnantioselective Hydrogenative DesymmetrizationdetourcatalystchiralBicyclic Imidesenantiomeric exesssesstereochemicallyCpbicyclic imides

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