ic6b02317_si_002.cif (463.87 kB)

[CH₃NH₃]₂Ag₄Sn^IV₂Sn^IIS₈: An Open-Framework Mixed-Valent Chalcogenidostannate

dataset

posted on 2016-10-21, 17:56 authored by Bo Zhang, Jun Li, Cheng-Feng Du, Mei-Ling Feng, Xiao-Ying Huang

An open-framework chalcogenidostannate, namely, [CH₃NH₃]₂Ag₄Sn^IV₂Sn^IIS₈ (1), has been solvothermally synthesized and structurally characterized, which represents the first organically templated three-dimensional (3D) Ag–Sn–S compound containing the mixed valence of Sn(IV)/Sn(II) and displays visible-light-driven photocatalytic activity for degradation of crystal violet (CV).