ic034080u_si_001.cif (23.38 kB)
X-ray Structure and Variable Temperature NMR Spectra of [meso-Triarylcorrolato]copper(III)
dataset
posted on 2003-07-03, 00:00 authored by Christian Brückner, Raymond P. Briñas, Jeanette A. Krause BauerThe diamagnetic square planar d8 complexes [meso-arylcorrolato]copper(III) become paramagnetic upon warming, indicative of the
equilibrium between the [corrolato]copper(III) and the [corrolato]+•
copper(II) forms of the complex. [meso-Triphenylcorrolato]copper(III) was structurally characterized and found to be saddled.