ol060871z_si_001.cif (14.03 kB)
Unexpected One-Pot Method to Synthesize Spiro[fluorene-9,9‘-xanthene] Building Blocks for Blue-Light-Emitting Materials
dataset
posted on 2006-06-22, 00:00 authored by Ling-Hai Xie, Feng Liu, Chao Tang, Xiao-Ya Hou, Yu-Ran Hua, Qu-Li Fan, Wei HuangAn unexpected one-pot synthetic approach toward spiro[fluorene-9,9‘-xanthene] (SFX) under excessive MeSO3H conditions has been developed.
The key step involves a thermodynamically controlled cyclization reaction. Blue-light-emitting materials based on SFX building blocks that
exhibit high thermal stability have also been synthesized.