posted on 2017-05-31, 00:00authored byQuentin Jacquet, Arnaud Perez, Dmitry Batuk, Gustaaf Van Tendeloo, Gwenaëlle Rousse, Jean-Marie Tarascon
Searching
for novel high-capacity electrode materials combining
cationic and anionic redox processes is an ever-growing activity within
the field of Li-ion batteries. In this respect, we report on the exploration
of the Li3RuyNb1–yO4 (0 ≤ y ≤
1) system with an O/M ratio of 4 to maximize the number of oxygen
lone pairs, responsible for the anionic redox. We show that this system
presents a very rich crystal chemistry with the existence of four
structural types, which derive from the rocksalt structure but differ
in their cationic arrangement, creating either zigzag, helical, jagged
chains or clusters. From an electrochemical standpoint, these compounds
are active on reduction via a classical cationic insertion process.
The oxidation process is more complex, because of the instability
of the delithiated phase. Our results promote the use of the rich
Li3MO4 family as a viable platform for a better
understanding of the relationships between structure and anionic redox
activity.