ja208256u_si_011.cif (25.23 kB)
Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins
dataset
posted on 2012-01-18, 00:00 authored by Zhenjie Zhang, Linping Zhang, Lukasz Wojtas, Mohamed Eddaoudi, Michael J. Zaworotkomeso-Tetra(N-methyl-4-pyridyl)porphine
tetratosylate (TMPyP) templates the synthesis of six new metal–organic
materials by the reaction of benzene-1,3,5-tricarboxylate with transition
metals, five of which exhibit HKUST-1 or tbo topology
(M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in
octahemioctahedral cages and can serve as size-selective heterogeneous
catalysts for oxidation of olefins.