ol5027816_si_001.cif (33.83 kB)
Synthesis of Sexithiophene-Bridged Cage Compound: A New Class of Three-Dimensionally Expanded Oligothiophenes
dataset
posted on 2014-11-21, 00:00 authored by Kazuhiko Adachi, Yasukazu Hirao, Kouzou Matsumoto, Takashi Kubo, Hiroyuki KurataA bicyclo-type cage-shaped compound
consisting of three sexithiophenes
was successfully synthesized and characterized by NMR, HRMS, and X-ray
crystallographic analysis. The strained cage architecture was reflected
in the blue-shifted absorption spectrum relative to its linear analogue.
Intramolecular interaction between three-dimensionally fixed sexithiophenes
was suggested by electrochemical analysis.
