am201638a_si_001.pdf (275.16 kB)
Surface Functionalization of Alumina Ceramic Foams with Organic Ligands
journal contribution
posted on 2012-02-22, 00:00 authored by Horacio Comas, Vincent Laporte, Françoise Borcard, Pascal Miéville, Franziska Krauss Juillerat, Marc A. Caporini, Urs T. Gonzenbach, Lucienne Juillerat-Jeanneret, Sandrine Gerber-LemaireDifferent anchoring groups have been studied with the
aim of covalently
binding organic linkers to the surface of alumina ceramic foams. The
results suggested that a higher degree of functionalization was achieved
with a pyrogallol derivative – as compared to its catechol
analogue – based on the XPS analysis of the ceramic surface.
The conjugation of organic ligands to the surface of these alumina
materials was corroborated by DNP-MAS NMR measurements.