jo060527f_si_003.cif (17.94 kB)
Structures of 1-(Arylseleninyl)naphthalenes: O, G, and Y Dependences in 8-G-1-[p-YC6H4Se(O)]C10H6
dataset
posted on 2006-07-21, 00:00 authored by Satoko Hayashi, Hideki Wada, Takashi Ueno, Waro NakanishiStructures of 8-G-1-[p-YC6H4Se(O)]C10H6 [1 (G = H), 2 (G = F), 3 (G = Cl), and 4 (G = Br): Y =
H, OMe, OCH2Ph, t-Bu, Me, Cl, and NO2] and (1-C10H7)2SeO (5) are investigated by the X-ray
crystallographic analysis. Structures of 1 are all A with regard to the naphthyl group (1 (A)), where the
Se−CAr and Se−O bonds are perpendicular to and parallel to the naphthyl plane, respectively. Those of
2−4 are also A. Since structures of 8-G-1-(p-YC6H4Se)C10H6 [7 (G = F), 8 (G = Cl), and 9 (G = Br)]
are all B, the results exhibit that B of 7−9 change dramatically to A of 2−4 with the introduction of O
atoms. The factor to determine the A structures of 1−4 by O is called O dependence. The origin of the
O dependence is the nonbonded np(O)- - -π(Nap) interaction, which results in CT from np(O) to π(Nap)
since O in 1−4 is highly electron rich due to the polar Se+=O- bond and π(Nap) acts as an acceptor.
There are two types of np(O)'s, npy(O) and npz(O), if the directions of the Se−O bond and the p-orbitals
of π(Nap) are taken in the x- and z-axes, respectively. Double but independent np(O)- - -π(Nap) interactions
in 5 lead to 5 (AA). The conformation of the p-YC6H4Se group in 1 changes depending on Y (Y
dependence), although the effect is not strong. The Y dependence is explained on the basis of the magnitude
of CT of the np(O)→π(Ar) type in 1, in addition to the np(O)- - -π(Nap) interaction. The structure around
the SeO group in 1 is close to that of 5 (AA), if the accepting ability of the p-YC6H4Se group is similar
to that of the naphthyl group. A of 2−4 are further stabilized by the np(G)- - -σ*(Se−O) 3c−4e interactions,
which are called G dependence. QC calculations performed on the methyl analogues of 1−4 (11−14,
respectively) reproduced the observed structures, supported the above discussion, and revealed the energy
profiles. The energy-lowering effect of the O dependence would be close to the G dependence of the
nonbonded n(Br)- - -σ*(Se−O) 3c−4e interaction in 14 if the steric repulsion between Br and Se is
contained in the G dependence. The value is roughly predicted as 20 kJ mol-1. The structures of 1−5 are
well explained by O, G, and Y dependences.