Structure−Property Relationships for Two-Photon Absorbing Chromophores: Bis-Donor Diphenylpolyene and Bis(styryl)benzene Derivatives
2000-09-13T00:00:00Z (GMT) by
The two-photon absorption properties of a series of bis dialkylamino- or diarylamino-substituted diphenylpolyenes and bis(styryl)benzenes have been investigated. Two-photon absorption cross sections, <i>δ</i>, as large as 1420 × 10<sup>-50</sup> cm<sup>4</sup> s/photon-molecule have been observed for molecules with this general bis-donor structure. The effect of the type and length of the conjugated chain and of dialkylamino or diarylamino substitution on the position and magnitude of the peak two-photon absorptivity is reported. The transition dipole moments for the transitions between the ground state and the first excited singlet state (<i>M</i><sub>ge</sub>) and between the first and second excited singlet states (<i>M</i><sub>ee</sub><sub>‘</sub>) have been estimated using experimental data from the one- and two-photon spectra. It was found that increases in chain length result mainly in an increase in <i>M</i><sub>ge</sub>, whereas the addition of donor end groups or going from diphenylpolyene- to phenylene-vinylene-type bridges leads primarily to an increase in <i>M</i><sub>ee</sub><sub>‘</sub>. The trends in the energy of the lowest excited singlet states and in the transition moments for the diphenylpolyene series as a function of chain length are in agreement with those calculated by quantum mechanical methods. These results furnish a link between structural features in these classes of molecules and the electronic dipole couplings and state energies that control the strength of the two-photon absorption. In bis(aminophenyl)polyenes containing up to four double bonds (<i>m</i>) the lowest excited singlet state is a B<sub>u</sub> state, as opposed to the case of simple polyenes and diphenylpolyenes, for which it is an A<sub>g</sub> state for <i>m</i> > 2. The relationship of the state ordering in these systems with the observed values of the radiative and nonradiative decay rates is also discussed.