cg400538c_si_002.cif (214.11 kB)
Structural Diversities and Fluorescent and Photocatalytic Properties of a Series of CuII Coordination Polymers Constructed from Flexible Bis-pyridyl-bis-amide Ligands with Different Spacer Lengths and Different Aromatic Carboxylates
dataset
posted on 2013-08-07, 00:00 authored by Xiu-Li Wang, Jian Luan, Fang-Fang Sui, Hong-Yan Lin, Guo-Cheng Liu, Chuang XuThirteen
new CuII coordination polymers, namely, [Cu(3-dppa)(1,3,5-HBTC)]
(1), [Cu(3-dpha)(1,3,5-HBTC)(H2O)]·H2O (2), [Cu3(3-dpsea)(1,3,5-BTC)2(H2O)5]·4H2O (3), [Cu(3-dpba)(1,2-BDC)]·H2O
(4), [Cu(3-dpha)(1,2-BDC)] (5), [Cu(3-dpsea)(1,2-BDC)]·H2O (6), [Cu2(3-dpyp)(1,3-BDC)2(H2O)4]·3H2O (7), [Cu(3-dppa)(1,3-BDC)(H2O)]·2H2O (8), [Cu(3-dppia)(1,3-BDC)(H2O)2]·2H2O (9), [Cu2(3-dpsea)2(1,3-BDC)2(H2O)2]·7H2O (10), [Cu(3-dpba)(1,4-NDC)]·3H2O (11), [Cu(3-dpyh)(1,4-NDC)(H2O)]·3H2O (12), [Cu(3-dpyh)0.5(1,4-NDC)]·H2O (13), have been purposefully synthesized under hydrothermal conditions
[3-dppa = N,N′-di(3-pyridyl)propanediamide,
3-dpba = N,N′-di(3-pyridyl)butanediamide,
3-dpha = N,N′-di(3-pyridyl)hexanedioicdiamide,
3-dppia = N,N′-di(3-pyridyl)pimelicdiamide,
3-dpsea = N,N′-di(3-pyridyl)sebacicdiamide,
3-dpyp = N,N′-di(3-pyridinecarboxamide)-1,3-propane,
3-dpyh = N,N′-di(3-pyridinecarboxamide)-1,6-hexane,
1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid, 1,2-H2BDC = 1,2-benzenedicarboxylic acid, 1,3-H2BDC =
1,3-benzenedicarboxylic acid and 1,4-H2NDC = 1,4-naphthalenedicarboxylic
acid]. Complexes 1–3 based on the
same auxiliary ligand show various structures. Complex 1 features a one-dimensional (1D) ∞-like double-chain structure,
which consists of a [Cu-1,3,5-HBTC]n chain
and [Cu-3-dppa]n meso-helical chain. Complex 2 possesses a (2,4) undulated
honeycomb (hcb) net. Complex 3 is a 3-fold interpenetrating
three-dimensional (3D) framework, which shows trinodal (2,3,3)-connected
topology with the Schläfli symbol of (10·122)2(103)2(12). Complexes 4–6 with 1,2-BDC as secondary ligand exhibit different
two-dimensional (2D) layer structures. Complex 4 exhibits
a 2D (2,4)-connected (4·124·14)(4) net. Complexes 5 and 6 have similar structures and show 2D networks
with undulated sql topology. For complexes 7–10 based on 1,3-BDC secondary ligand, complex 7 shows a 1D zigzag chain, while complexes 8–10 have similar wave-like 2D structures. When 1,4-NDC was
used as the auxiliary ligand, complex 11 is a 2D puckered
(4,4) network, complex 12 reveals a 4-connected topology
with the point symbol of (44·62), while
complex 13 exhibits a 3-fold interpenetrating 3D α-Po
framework. The structural diversity indicates that the bis-pyridyl-bis-amide
ligands with different spacers and the aromatic polycarboxylates play
important roles in tuning the dimensionalities and structures of the
title complexes. The fluorescent and photocatalytic properties for 1–13 have also been investigated in detail.
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13 exhibitsComplex 4 exhibitsComplexes 5Complex 1 featuresDifferent Spacer LengthsCuII Coordination Polymers Constructedshow 2 D networks2 D1 D zigzag chainPhotocatalytic Propertiessql topology2BDClayer structures3BTCBDCComplex 3Different Aromatic CarboxylatesThirteenpoint symbolNDCligand exhibitCuII coordination polymersStructural Diversitiesphotocatalytic propertiesComplex 2ligand show2NDCtitle complexes
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