ol7b03344_si_001.pdf (3.94 MB)
Silver(I)- and Base-Mediated [3 + 3]-Cycloaddition of C,N‑Cyclic Azomethine Imines with Aza-oxyallyl Cations
journal contribution
posted on 2017-12-07, 15:50 authored by Xiao Cheng, Xia Cao, Jun Xuan, Wen-Jing XiaoA silver(I) and base-mediated [3
+ 3]-cycloaddition reaction of
in situ generated C,N-cyclic azomethine
imines with in situ formed aza-oxyallyl cations is reported. This
one-pot cycloaddition process shows broad substrate scope an excellent
functional group tolerance and provides the corresponding biologically
important isoquinoline-fused triazines in good to excellent yields.