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Selective Partial Hydrogenation of Methyl Linoleate Using Highly Active Palladium Nanoparticles in Polyethylene Glycol
journal contribution
posted on 2017-01-11, 17:20 authored by Wei Liu, Lige Xu, Guanghui Lu, Hua ZhangPartial
hydrogenation of carbon–carbon double bonds is among
one of the approaches to improve the low oxidative stability of vegetable
biodiesel, which is an important drawback in biodiesel technology.
In the current work, we developed an efficient two-phase catalytic
system utilizing Pd(OAc)2 dissolved in polyethylene glycol
(PEG) that in situ generates palladium nanoparticles
in order to promote a selective partial hydrogenation reaction of
methyl linoleate into mono-hydrogenated compounds
while avoiding the generation of saturated compounds. High yield of
methyl oleate was also obtained by hydrogenation of sunflower oil
biodiesel using the same catalytic system. Through evaluating the
palladium nanoparticles by TEM analysis, it is observed that 4 nm
palladium nanoparticles generated in situ in PEG4000
showed high selectivity both for the partial hydrogenation of methyl
linoleate and sunflower oil biodiesel.