ol6b02197_si_001.pdf (944.36 kB)
Schincalide A, a Schinortriterpenoid with a Tricyclo[5.2.1.01,6]decane-Bridged System from the Stems and Leaves of Schisandra incarnate
journal contribution
posted on 2016-08-26, 20:13 authored by Ming Zhou, Ye Liu, Jian Song, Xiao-Gang Peng, Qi Cheng, Hui Cao, Ming Xiang, Han-Li RuanSchincalide A (1), an
unprecedented schinortriterpenoid possessing a tricyclo[5.2.1.01,6]decane-bridged system, was isolated from the stems and
leaves of Schisandra incarnate. The
structure with absolute configuration of 1 was determined
by extensive spectroscopic analyses and single-crystal X-ray diffraction.
A hypothetical biosynthetic pathway of 1 was postulated.