om401031h_si_001.cif (215.4 kB)
Palladium–Osmium Heterometallic Clusters Containing N‑Heterocyclic Carbene Ligands
dataset
posted on 2013-12-23, 00:00 authored by Yu Liu, Rakesh Ganguly, Han Vinh Huynh, Weng Kee LeongThe
room-temperature reaction of [Os3(CO)12] with
[PdCl(allyl)(NHC)], where NHC (N-heterocyclic carbene) = SIPr
[N,N′-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene]
or IPr [N,N′-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene],
afforded Pd–Os mixed metal clusters with formulas of [PdnOs3(CO)12(NHC)n] (n = 1–3). These
are the first examples of Pd–Os heterometallic clusters containing
NHC ligands, and they have all been structurally characterized. In
all these clusters, the metal cores are raftlike, with carbonyl ligands
bridging all the Os–Pd edges.